1 Temperature & heat
Temperature measures average particle kinetic energy; heat is energy transferred due to a temperature difference. Heat moves by conduction, convection and radiation. The kelvin scale starts at absolute zero (−273.15 °C).
Heat, energy, entropy and engines — central to mechanical and chemical engineering.
Temperature measures average particle kinetic energy; heat is energy transferred due to a temperature difference. Heat moves by conduction, convection and radiation. The kelvin scale starts at absolute zero (−273.15 °C).
The first law is conservation of energy for thermal systems: ΔU = Q − W — the change in internal energy equals heat added minus work done by the system. Energy is never created or destroyed, only transformed.
The second law states that the entropy (disorder) of an isolated system never decreases. Heat flows spontaneously from hot to cold, and no engine can be 100% efficient. This sets the direction of time and limits all real machines.
A heat engine converts heat into work between hot and cold reservoirs. The ideal Carnot efficiency is 1 − T_cold/T_hot (in kelvin) — the theoretical maximum. Real engines (car, turbine, refrigerator cycles) fall short due to friction and irreversibility.
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